Autoionizing states of atoms calculated using generalized sturmians

Research output: Chapter in Book/Report/Conference proceedingBook chapterResearchpeer-review

Standard

Autoionizing states of atoms calculated using generalized sturmians. / Avery, James Emil; Avery, John Scales.

Advances in quantum chemistry. ed. / John R. Sabin; Errki J. Brändas. Academic Press, 2005. p. 103-119 (Advances in Quantum Chemistry, Vol. 49).

Research output: Chapter in Book/Report/Conference proceedingBook chapterResearchpeer-review

Harvard

Avery, JE & Avery, JS 2005, Autoionizing states of atoms calculated using generalized sturmians. in JR Sabin & EJ Brändas (eds), Advances in quantum chemistry. Academic Press, Advances in Quantum Chemistry, vol. 49, pp. 103-119. https://doi.org/10.1016/S0065-3276(05)49002-4

APA

Avery, J. E., & Avery, J. S. (2005). Autoionizing states of atoms calculated using generalized sturmians. In J. R. Sabin, & E. J. Brändas (Eds.), Advances in quantum chemistry (pp. 103-119). Academic Press. Advances in Quantum Chemistry, Vol.. 49 https://doi.org/10.1016/S0065-3276(05)49002-4

Vancouver

Avery JE, Avery JS. Autoionizing states of atoms calculated using generalized sturmians. In Sabin JR, Brändas EJ, editors, Advances in quantum chemistry. Academic Press. 2005. p. 103-119. (Advances in Quantum Chemistry, Vol. 49). https://doi.org/10.1016/S0065-3276(05)49002-4

Author

Avery, James Emil ; Avery, John Scales. / Autoionizing states of atoms calculated using generalized sturmians. Advances in quantum chemistry. editor / John R. Sabin ; Errki J. Brändas. Academic Press, 2005. pp. 103-119 (Advances in Quantum Chemistry, Vol. 49).

Bibtex

@inbook{64cc7570229711ddbc23000ea68e967b,
title = "Autoionizing states of atoms calculated using generalized sturmians",
abstract = "The generalized Sturmian method is applied to autoionizing statesof atoms and ions. If the Goscinskian basis sets allow for a sufficientamount of angular correletion, the calculated energies of doubly-excited(autoionizing) states are found to agree well with the few availableexperimental energies. A large-Z approximation is discussed, and simpleformulas are derived which are valid not only for autoionizing states,but for all states of an isoelectronic atomic series. Diagonalizationof a small block of the interelectron repulsion matrix yields roots that can be used for a wide range of Z values.",
author = "Avery, {James Emil} and Avery, {John Scales}",
year = "2005",
doi = "10.1016/S0065-3276(05)49002-4",
language = "English",
isbn = "978-0-12-034849-7",
series = "Advances in Quantum Chemistry",
publisher = "Academic Press",
pages = "103--119",
editor = "Sabin, {John R.} and Br{\"a}ndas, {Errki J.}",
booktitle = "Advances in quantum chemistry",
address = "United States",

}

RIS

TY - CHAP

T1 - Autoionizing states of atoms calculated using generalized sturmians

AU - Avery, James Emil

AU - Avery, John Scales

PY - 2005

Y1 - 2005

N2 - The generalized Sturmian method is applied to autoionizing statesof atoms and ions. If the Goscinskian basis sets allow for a sufficientamount of angular correletion, the calculated energies of doubly-excited(autoionizing) states are found to agree well with the few availableexperimental energies. A large-Z approximation is discussed, and simpleformulas are derived which are valid not only for autoionizing states,but for all states of an isoelectronic atomic series. Diagonalizationof a small block of the interelectron repulsion matrix yields roots that can be used for a wide range of Z values.

AB - The generalized Sturmian method is applied to autoionizing statesof atoms and ions. If the Goscinskian basis sets allow for a sufficientamount of angular correletion, the calculated energies of doubly-excited(autoionizing) states are found to agree well with the few availableexperimental energies. A large-Z approximation is discussed, and simpleformulas are derived which are valid not only for autoionizing states,but for all states of an isoelectronic atomic series. Diagonalizationof a small block of the interelectron repulsion matrix yields roots that can be used for a wide range of Z values.

U2 - 10.1016/S0065-3276(05)49002-4

DO - 10.1016/S0065-3276(05)49002-4

M3 - Book chapter

SN - 978-0-12-034849-7

T3 - Advances in Quantum Chemistry

SP - 103

EP - 119

BT - Advances in quantum chemistry

A2 - Sabin, John R.

A2 - Brändas, Errki J.

PB - Academic Press

ER -

ID: 4078577